Green catalyst destroys pervasive wastewater pollutants

A new catalyst has been created to destroy nitrophenols, some of the most pervasive and toxic pollutants in wastewater discharges.

The catalyst was developed by scientists at Carnegie Mellon University in Pittsburgh who say it can rapidly destroy the chemicals in an environmentally friendly manner.

Nitrophenols are man-made pollutants that mostly originate from wastewater discharges from the dye, pesticide and ammunition industries as well as from various chemical-manufacturing plants. They are also found in diesel exhaust particles. Thousands of tons of these agents are produced yearly by countries around the world. Registered as priority pollutants by the EPA, they are toxic to aquatic life. They produce immediate toxic effects to the nervous system, and some reports have implicated them as possible endocrine disruptors.

Many of these compounds cannot be destroyed by existing means.

The new catalyst, one of a family of catalysts called Fe-TAMLs (TAML stands for tetra-amido macrocyclic ligand), works with hydrogen peroxide. Its "green" design is based on elements used naturally in biochemistry. Fe-TAMLs were discovered by Terence Collins, the Thomas Lord Professor of Chemistry and director of the Institute for Green Oxidation Chemistry at the Mellon College of Science (MCS) at Carnegie Mellon.

His group has developed an extensive suite of these catalysts to provide clean, safe alternatives to existing industrial practices, as well as ways to remediate other pressing problems that currently lack solutions.
"Fe-TAMLs are much easier to use in destroying nitrophenols because they work at ambient temperatures and neutral pH," said Collins. "Existing detoxification methods are inefficient and work only under acidic conductions. Our method can be used over a much broader pH range, including wastewater pH conditions."

Fe-TAMLs already have shown promise in killing a simulant of a biological warfare agent (anthrax), reducing fuel pollutants, treating pulp and paper processing byproducts, and detoxifying pesticides.

A major goal is to develop Fe-TAMLs as a safe, cost-effective means of global water decontamination.

These findings were presented by Collins and members of his laboratory at conference this week at the 230th ACS meeting at the University.

David Hopkins.



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